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The structure of unsolvated neopentyl sodium has been reported in Angewandte Chemie (🔎 https://ccdc-info.com/4lmqyrL), revealing a rare tetrameric motif. When combined with N,N,N',N'',N''-pentamethyldiethylenetriamine, it allows for the direct metalation of challenging non-activated arenes and alkenes. 🔗 CSD Entry SAGDEO: https://ccdc-info.com/4m42f35 #FeaturedStructureFriday #Crystallography | Cambridge Crystallographic Data Centre (CCDC)
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